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{"type":"standard","title":"Vilsmeier reagent","displaytitle":"Vilsmeier reagent","namespace":{"id":0,"text":""},"wikibase_item":"Q27894258","titles":{"canonical":"Vilsmeier_reagent","normalized":"Vilsmeier reagent","display":"Vilsmeier reagent"},"pageid":58895181,"thumbnail":{"source":"https://upload.wikimedia.org/wikipedia/commons/thumb/2/26/VilsReagent.png/330px-VilsReagent.png","width":320,"height":233},"originalimage":{"source":"https://upload.wikimedia.org/wikipedia/commons/2/26/VilsReagent.png","width":412,"height":300},"lang":"en","dir":"ltr","revision":"1269862280","tid":"1ad68a64-d441-11ef-afc5-2438e1f89eba","timestamp":"2025-01-16T19:35:56Z","description":"Chemical compound","description_source":"local","content_urls":{"desktop":{"page":"https://en.wikipedia.org/wiki/Vilsmeier_reagent","revisions":"https://en.wikipedia.org/wiki/Vilsmeier_reagent?action=history","edit":"https://en.wikipedia.org/wiki/Vilsmeier_reagent?action=edit","talk":"https://en.wikipedia.org/wiki/Talk:Vilsmeier_reagent"},"mobile":{"page":"https://en.m.wikipedia.org/wiki/Vilsmeier_reagent","revisions":"https://en.m.wikipedia.org/wiki/Special:History/Vilsmeier_reagent","edit":"https://en.m.wikipedia.org/wiki/Vilsmeier_reagent?action=edit","talk":"https://en.m.wikipedia.org/wiki/Talk:Vilsmeier_reagent"}},"extract":"The Vilsmeier reagent is an organic compound with the formula [(CH3)2NCHCl]Cl. It is a salt consisting of the N,N-dimethyliminium cation ([(CH3)2N=CHCl]+) and chloride anion. Depending on the particular reaction, the anion can vary. In typical POCl3-based reactions, the anion is PO2Cl2−. The iminium cation [(CH3)2N=CHCl]+ is the reactive component of interest. This iminium species is a derivative of the imidoyl chloride CH3N=CHCl. Analogues of this particular reagent are generated when tertiary amides other than DMF are treated with POCl3.","extract_html":"
The Vilsmeier reagent is an organic compound with the formula [(CH3)2NCHCl]Cl. It is a salt consisting of the N,N-dimethyliminium cation ([(CH3)2N=CHCl]+) and chloride anion. Depending on the particular reaction, the anion can vary. In typical POCl3-based reactions, the anion is PO2Cl2−. The iminium cation [(CH3)2N=CHCl]+ is the reactive component of interest. This iminium species is a derivative of the imidoyl chloride CH3N=CHCl. Analogues of this particular reagent are generated when tertiary amides other than DMF are treated with POCl3.
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{"type":"standard","title":"Wolverton railway station","displaytitle":"Wolverton railway station","namespace":{"id":0,"text":""},"wikibase_item":"Q1824147","titles":{"canonical":"Wolverton_railway_station","normalized":"Wolverton railway station","display":"Wolverton railway station"},"pageid":1931267,"thumbnail":{"source":"https://upload.wikimedia.org/wikipedia/commons/thumb/9/90/View_of_Wolverton_railway_station_September_2020.jpg/330px-View_of_Wolverton_railway_station_September_2020.jpg","width":320,"height":213},"originalimage":{"source":"https://upload.wikimedia.org/wikipedia/commons/9/90/View_of_Wolverton_railway_station_September_2020.jpg","width":4617,"height":3078},"lang":"en","dir":"ltr","revision":"1286525634","tid":"b848a320-1de4-11f0-8cf6-566088071c46","timestamp":"2025-04-20T12:41:03Z","description":"Railway station in Milton Keynes, England","description_source":"local","coordinates":{"lat":52.0653,"lon":-0.80357},"content_urls":{"desktop":{"page":"https://en.wikipedia.org/wiki/Wolverton_railway_station","revisions":"https://en.wikipedia.org/wiki/Wolverton_railway_station?action=history","edit":"https://en.wikipedia.org/wiki/Wolverton_railway_station?action=edit","talk":"https://en.wikipedia.org/wiki/Talk:Wolverton_railway_station"},"mobile":{"page":"https://en.m.wikipedia.org/wiki/Wolverton_railway_station","revisions":"https://en.m.wikipedia.org/wiki/Special:History/Wolverton_railway_station","edit":"https://en.m.wikipedia.org/wiki/Wolverton_railway_station?action=edit","talk":"https://en.m.wikipedia.org/wiki/Talk:Wolverton_railway_station"}},"extract":"Wolverton railway station serves Wolverton, a constituent town of Milton Keynes, Buckinghamshire, England. The station is on the West Coast Main Line, about 52 miles (84 km) from Euston, between Milton Keynes Central and Northampton. The station is one of the seven stations serving the Milton Keynes urban area.","extract_html":"
Wolverton railway station serves Wolverton, a constituent town of Milton Keynes, Buckinghamshire, England. The station is on the West Coast Main Line, about 52 miles (84 km) from Euston, between Milton Keynes Central and Northampton. The station is one of the seven stations serving the Milton Keynes urban area.
"}